We neglected the term dM4. If we include it, free energy is no longer a sum of independent terms--fluctuations interact!
When fluctuations are small, we can expand this term. When they are not--we are out of luck!Close enough to critical point only interactions of long wavelength fluctuations determine the properties. But the long wavelength limit is described by Landau Hamiltonian!
In other words, near critical point we start from Landau expression, calculate fluctuations and their interactions--and obtain everything!
In particular, for scalar order parameter all systems can be described by partition function
(5) |
Fluctuations with the wavelength do not ``feel'' the critical point. The only fluctuations that do, are those with
© 1997 Boris Veytsman and Michael Kotelyanskii